Search results for "Waste generation"
showing 7 items of 7 documents
Improvement of the atomic fluorescence determination of mercury by using multicommutation
2002
Atomic fluorescence spectrometry (AFS) determination of Hg has been improved by exploiting the possibilities of the multicommutation approach in order to outline a fully mechanised system which supplies the same sensitivity as the use of continuous measurements, reducing drastically the reagents consumed and waste generation. The use of multicommutation with a simultaneous reduction of the liquid–gas separator volume and the insertion point modification of argon transport gas provides a sensitivity of the AFS measurements of 300 mV ng−1 ml (using a full scale of 1000 mV), a limit of detection (3 s) of 1.3 ng l−1 and relative standard deviation values below 0.1% for 10 independent measuremen…
A clean method for flow injection spectrophotometric determination of cyclamate in table sweeteners
2005
Abstract A flow system based on the multicommutation is proposed for fast and clean determination of cyclamate. The procedure exploits the reaction of cyclamate with nitrite in acidic medium and the spectrophotometric determination of the excess of nitrite by iodometry. The flow system was designed with a set of solenoid micro-pumps to minimize reagent consumption and waste generation. The detection limit was estimated as 30 μmol L −1 (99.7% confidence level) with linear response ranging up to 3.0 mmol L −1 . The coefficient of variation was estimated as 1.7% for a solution containing 2.0 mmol L −1 cyclamate ( n = 20). About 60 samples can be analyzed per hour, consuming only 3 mg KI and 1…
Green Spectroscopy: A Scientometric Picture
2009
ABSTRACT The state of the art of green spectroscopy, as a sustainable and friendly alternative to the classical spectrometric methods of analysis, has been established from the evaluation of the scientific literature published about this topic in the frame of the so-called Green Chemistry paradigm. Special attention has been paid to the fact that keywords like Green Analytical Chemistry, environmentally friendly, or clean analytical method or sustainable analytical chemistry are far from being commonly used in analytical studies. In spite of this fact there are numerous studies that provide direct analytical methodologies, or a reduction of reagents consumption or waste generation, the recy…
Direct determination of polymerised triacylglycerides in deep-frying vegetable oil by near infrared spectroscopy using Partial Least Squares regressi…
2012
Abstract A green method for the determination of polymerised triacylglyceride (PTG) in deep-frying vegetable oils of different botanic origin has been developed employing near infrared (NIR) spectroscopy and Partial Least Squares (PLS) regression. Four different types of oil were heated during several hours, with and without the addition of foodstuff. NIR transmission spectra were obtained directly from sample aliquots stored in glass vials, thus avoiding the consumption of solvents and minimising waste generation. Variables employed for building the PLS models were selected applying interval PLS (iPLS) as well as Uninformative Variable Elimination-PLS (UVE-PLS). A global PLS model using sp…
Multicommutation ATR-FTIR: determination of sodium alpha-olefin sulfonate in detergent formulations
2004
Abstract The mechanization of attenuated total reflectance measurements (ATR) in Fourier Transform Infrared spectrometry (FTIR) through the use of multicommutation has been evaluated in order to reduce the sample consumption and waste generation also avoiding risks of cells breaking. A new multicommutation ATR-FTIR procedure has been proposed for the determination of sodium alpha-olefin sulfonate (AOS) in liquid detergent formulations. The main advantages of this method are the low consumption of sample (96 ml per 100 determinations) and the analytical throughput (23 h −1 versus 15 h −1 for the manual mode). Results obtained for reference samples containing 7.52% to 9.52% (w/w) of AOS are i…
Design for recyclability and the avoidance of waste: the case of printed paper in Germany
1999
This paper discusses the generation of process waste in printed paper recycling and some factors affecting the amount of de-inking waste. The effects on waste generation by paper grades, which are designed for improved recyclability, are pointed out. The amount of waste generated is considered as the improvement in recyclability. This corresponds to a reduction in the use of materials that cannot be recycled, which, in the case of paper means lowering their mineral content. Two scenarios of a dynamic model of the fluxes of printed paper in Germany between 1993 and 2000 are used to analyse the amount of waste generated. No product changes are assumed in the first scenario, whereas improved …
Partial least squares-near infrared determination of pesticides in commercial formulations
2007
Abstract A solvent free, fast and environmentally friendly near infrared-based methodology (NIR) was developed for pesticide determination in commercially available formulations. This methodology was based on the direct measurement of the diffuse reflectance spectra of solid samples and a multivariate calibration model (partial least squares, PLS) to determine the active principle concentration in commercial formulations. The PLS calibration set was built on using the spiked samples by mixing different amounts of pesticide standards and powdered samples. Buprofezin, Diuron and Daminozide were used as test analytes. Concentration of Buprofezin in the samples was calculated employing a 4-fact…